Ion solvation dynamics in supercritical water

被引：18

作者：

Biswas, R

Bagchi, B ^{[1
]}

机构：

[1] Indian Inst Sci, Solid State & Struct Chem Unit, Bangalore 560012, Karnataka, India

[2] Indian Inst Sci, Jawaharlal Nehru Ctr Adv Sci Res, Bangalore 560012, Karnataka, India

来源：

CHEMICAL PHYSICS LETTERS | 1998年 / 290卷 / 1-3期

关键词：

D O I：

10.1016/S0009-2614(98)00460-6

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

A theoretical study of ionic solvation dynamics in supercritical water is presented. The short-time decay of the calculated equilibrium solvation energy time correlation function (S-E(t)) is found to be in good agreement with the recent computer simulation results, The simulated long-time decay is, however, somewhat slower than that which is predicted by the present theory. Two plausible molecular explanations for the slow long-time decay of S-E(t) are offered. (C) 1998. Published by Elsevier Science B.V. All rights reserved.

引用

页码：223 / 228

页数：6

共 32 条

[1]

BAGCHI B, 1991, ADV CHEM PHYS, V80, P1

[2] DYNAMICS OF SOLVATION AND CHARGE-TRANSFER REACTIONS IN DIPOLAR LIQUIDS [J].