'Locking' dendrimer conformation through metal coordination

被引：16

作者：

Rauckhorst, MR ^{[1
]}

Wilson, PJ ^{[1
]}

Hatcher, SA ^{[1
]}

Hadad, CM ^{[1
]}

Parquette, JR ^{[1
]}

机构：

[1] Ohio State Univ, Dept Chem, Columbus, OH 43210 USA

来源：

TETRAHEDRON | 2003年 / 59卷 / 22期

基金：

美国国家科学基金会;

关键词：

dendrimer conformation; syn-syn conformation; copper(II) metal centers;

D O I：

10.1016/S0040-4020(03)00460-5

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Chiral intramolecularly hydrogen-bonded dendrons that fold into a dynamically biased helical conformation can be 'locked' in kinetically controlled conformations by coordination to copper(II) metal centers. Covalent bonding of each pyridine-2,6-dicarboxamide repeat unit of the dendrons to a copper metal center forces this subunit to exist in only the syn-syn conformation and dramatically rigidifies the dendron structure. (C) 2003 Elsevier Science Ltd. All rights reserved.

引用

页码：3917 / 3923

页数：7

共 54 条

[1] SYNTHESIS AND COORDINATION CHEMISTRY OF 2 PENTA-AZAMACROCYCLES CONTAINING A 1,4-PIPERAZINE BACKBONE - CRYSTAL-STRUCTURE DETERMINATIONS OF 6,12-DIOXO-1,5,13,17,22-PENTA-AZATRICYCLO[15.2.2.17,11]DOCOSA-7(22),8,10-TRIENE AND 1,5,13,17,22-PENTA-AZATRICYCLO[15.2.2.17,11]DOCOSA-7(22),8,10-TRIENENICKEL(II) PERCHLORATE2 [J].