1,4-Di(1,2,3-triazol-1-yl)butane as building block for the preparation of the iron(II) spin-crossover 2D coordination polymer

被引：159

作者：

Bronisz, R ^{[1
]}

机构：

[1] Univ Wroclaw, Fac Chem, PL-50383 Wroclaw, Poland

来源：

INORGANIC CHEMISTRY | 2005年 / 44卷 / 13期

关键词：

D O I：

10.1021/ic050449z

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The novel bidentate ligand 1, 4-di(1 2,3-triazol-1-yl) butane (bbtr) reacts with Fe(CIO4)(2)(.)6H(2)O to form the 2D coordination polymer with (3,6) network topology. The {[Fe(bbtr)(3)](CIO4)(2)}(infinity) represents an example of spin-crossover material based on 1,2,3-triazole as donor group, and displays an abrupt spin transition accompanied by a thermal hysteresis loop (T-1/2(down arrow) = 101 K and T-1/2(up arrow) = 109 K).

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页码：4463 / 4465

页数：3

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