Differentiation between 1,2,4,5-tetraoxanes and 1,2,4,5,7,8-hexaoxonanes using 1H and 13C NMR analyses

被引：22

作者：

Dong, YX ^{[1
]}

Vennerstrom, JL ^{[1
]}

机构：

[1] Univ Nebraska, Med Ctr, Coll Pharm, Dept Pharmaceut Sci, Omaha, NE 68198 USA

来源：

JOURNAL OF HETEROCYCLIC CHEMISTRY | 2001年 / 38卷 / 02期

关键词：

D O I：

10.1002/jhet.5570380224

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The proton and carbon resonance spectra of ten pairs of 1,2,4,5-tetraoxanes and 1,2,4,5,7,8-hexaoxonanes derived from acyclic and cyclic ketones have been recorded. A reliable method for distinguishing between 1,2,4,5-tetraoxanes and 1,2,4,5,7,8-hexaoxonanes by inspection of their chemical shifts, signal number, signal shape, and dynamic features has been developed. This method provides a rapid structural assignment of 1,2,4,5-tetraoxanes and 1,2,4,5,7,8-hexaoxonanes without using vapor pressure osmometry, isotope labeling or low temperature NMR techniques.

引用

页码：463 / 466

页数：4

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