Photocatalyst materials for water splitting

被引:339
作者
Kudo, A
机构
[1] Sci Univ Tokyo, Fac Sci, Dept Appl Chem, Shinjuku Ku, Tokyo 1628601, Japan
[2] JST, CREST, Kawaguchi, Saitama 3320012, Japan
关键词
photocatalyst; water splitting; visible light response; tantalate; hydrogen evolution; sulfide;
D O I
10.1023/A:1023480507710
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Various photocatalyst materials developed by the group of the present author are described. Alkali and alkaline earth tantalates have arisen as a new group of photocatalyst materials for splitting of water into H-2 and O-2 under ultraviolet irradiation. They showed activities even without co-catalysts such as Pt, being different from titanate photocatalysts. When NiO co-catalysts were loaded on the tantalate photocatalysts, the photocatalytic activities were markedly increased. Among the tantalates, NiO/NaTaO3 doped with La showed the highest activity. BiVO4, AgNO3, and TiO2 co-doped with Cr and Sb photocatalysts showed high activities for O-2 evolution in the presence of a sacrificial reagent (Ag+) under visible light irradiation (lambda > 420 nm). Pt/SrTiO3 co-doped with Cr and Sb or Ta, Pt/NaInS2, and Pt/AgInZn7S9 photocatalysts showed high activities for H-2 evolution from aqueous solutions containing reducing reagents under visible light irradiation. Furthermore, Cu- or Ni-doped ZnS photocatalysts showed H-2 evolution activities even without co-catalysts such as Pt.
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页码:31 / 38
页数:8
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