Direct fabrication of mesoporous carbons using in-situ polymerized silica gel networks as a template

被引:86
作者
Han, SJ
Kim, M
Hyeon, T
机构
[1] Seoul Natl Univ, Sch Chem Engn, Seoul 151744, South Korea
[2] Seoul Natl Univ, Natl Creat Res Initiat Ctr Oxide Nanocrystalline, Seoul 151744, South Korea
关键词
porous carbon; carbonization; BET surface area; porosity;
D O I
10.1016/S0008-6223(03)00072-1
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Mesoporous carbons were synthesized by in-situ polymerized silica gel networks as a template. The co-condensation of carbon precursor (sucrose) and silica precursor (sodium silicate) followed by heat treatment generated a carbon/silica nanocomposite. After etching the silica template, mesoporous carbons were obtained. Under optimum synthesis conditions a mesoporous carbon with a high surface area of >800 m(2)/g and a narrow pore size distribution centered at 3 nm was produced. The three-dimensionally interconnected silica structures effectively functioned as the template for the porous carbon materials. (C) 2003 Elsevier Science Ltd. All rights reserved.
引用
收藏
页码:1525 / 1532
页数:8
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