Linked amido-indenyl complexes of titanium

被引：72

作者：

Amor, F ^{[1
]}

Okuda, J ^{[1
]}

机构：

[1] UNIV MAINZ,INST ANORGAN CHEM & ANALYT CHEM,D-55099 MAINZ,GERMANY

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1996年 / 520卷 / 1-2期

关键词：

titanium; amido-indenyl ligand; alkyl derivatives;

D O I：

10.1016/0022-328X(96)06350-4

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Titanium complexes Ti(eta(5):eta(1)-C(9)H(6)SiMe(2)NCMe(3))X(2) (X = Cl, Me, CH(2)SiMe(3), CH(2)Ph) containing the tert-amido-functionalized indenyl ligand C(9)H(6)SiMe(2)NCMe(3) have been synthesized by the reaction of the dilithium derivative Li-2[C(9)H(6)SiMe(2)NCMe(3)] with TiCl3 (THF)(3) followed by oxidation or by the alkylation of the dichloro derivative. Unexpectedly, the reaction of C9H6(SiMe(3))(SiMe(2)Cl) with TiCl4 does not give Ti(eta(5)-C(9)H(6)SiMe(2)Cl)Cl-3.

引用

页码：245 / 248

页数：4

共 21 条

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