[3+2] Cycloadditions of Aryl Cyclopropyl Ketones by Visible Light Photocatalysis

被引：256

作者：

Lu, Zhan ^{[1
]}

Shen, Meihua ^{[1
]}

Yoon, Tehshik P. ^{[1
]}

机构：

[1] Univ Wisconsin, Dept Chem, Madison, WI 53706 USA

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2011年 / 133卷 / 05期

关键词：

RADICAL-ION PROBES; PHOTOREDOX CATALYSIS; FRAGMENTATION-CYCLIZATION; ALDEHYDES; REARRANGEMENTS; HETEROCYCLES;

D O I：

10.1021/ja107849y

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

We report a new method for the formal [3+2] reaction of aryl cyclopropyl ketones with olefins to generate highly substituted cyclopentane ring systems. The key initiation step in this process is the one-electron reduction of the ketone to the corresponding radical anion, which is accomplished using a photocatalytic system comprising Ru(bpy)(3)(2+), La(OTf)(3), and TMEDA.

引用

页码：1162 / 1164

页数：3

共 54 条

[1]

Alper PB, 1999, ANGEW CHEM INT EDIT, V38, P3186, DOI 10.1002/(SICI)1521-3773(19991102)38:21<3186::AID-ANIE3186>3.0.CO

[2]

2-E

[3] Intermolecular Addition of Glycosyl Halides to Alkenes Mediated by Visible Light [J].