Characterization of structural and surface properties of activated carbon fibers

被引:50
作者
Li, ZJ
Kruk, M
Jaroniec, M [1 ]
Ryu, SK
机构
[1] Kent State Univ, Dept Chem, Kent, OH 44242 USA
[2] Chungnam Natl Univ, Dept Chem Engn, Taejon, South Korea
关键词
adsorption; activated carbon fiber; microporosity;
D O I
10.1006/jcis.1998.5515
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Nitrogen adsorption isotherms on activated carbon fibers (ACFs) were measured at 77.3 K in the relative pressure range from 10(-7) to 0.995. The low relative pressure data are examined in detail in order to characterize the microporosity and the surface heterogeneity of the samples studied. The pore structure of ACFs was studied by using the ct, plot and DFT methods. Adsorption potential and adsorption energy distributions were also calculated. The results showed that ACFs are highly microporous and in some cases contain small mesopores (2-4 nm). ACFs exhibit a significant structural and energetic heterogeneity. (C) 1998 Academic Press
引用
收藏
页码:151 / 156
页数:6
相关论文
共 36 条
[1]  
[Anonymous], 1992, CONSTITUTION SLOVAK
[2]  
Bansal R.C., 1988, ACTIVE CARBON
[3]   Elucidating the porous structure of activated carbon fibers using direct and indirect methods [J].
Daley, MA ;
Tandon, D ;
Economy, J ;
Hippo, EJ .
CARBON, 1996, 34 (10) :1191-1200
[4]  
Dubinin M.M., 1975, Progress In Surface And Membrane Science, V9, P1, DOI [10.1016/B978-0-12-571809-7.50006-1, DOI 10.1016/B978-0-12-571809-7.50006-1]
[5]  
Dubinin M.M., 1947, DOKL AKAD NAUK SSSR, V55, P327
[6]  
GREGG SJ, 1982, ADSORPTION SURFACE
[7]   ENERGETIC HETEROGENEITY OF REFERENCE CARBONACEOUS MATERIALS [J].
HEUCHEL, M ;
JARONIEC, M ;
GILPIN, RK ;
BRAUER, P ;
VONDERSZOMBATHELY, M .
LANGMUIR, 1993, 9 (10) :2537-2546
[8]   METHOD FOR THE CALCULATION OF EFFECTIVE PORE-SIZE DISTRIBUTION IN MOLECULAR-SIEVE CARBON [J].
HORVATH, G ;
KAWAZOE, K .
JOURNAL OF CHEMICAL ENGINEERING OF JAPAN, 1983, 16 (06) :470-475
[9]  
Jankowska H., 1991, Active Carbon
[10]   EVALUATION OF ENERGETIC HETEROGENEITY AND MICROPOROSITY OF ACTIVATED CARBON-FIBERS ON THE BASIS OF GAS-ADSORPTION ISOTHERMS [J].
JARONIEC, M ;
GILPIN, RK ;
KANEKO, K ;
CHOMA, J .
LANGMUIR, 1991, 7 (11) :2719-2722