Facile preparation and photophysics of near-infrared luminescent lanthanide(III) monoporphyrinate complexes

被引：102

作者：

Foley, TJ

Harrison, BS

Knefely, AS

Abboud, KA

Reynolds, JR

Schanze, KS ^{[1
]}

Boncella, JM

机构：

[1] Univ Florida, Dept Chem, Gainesville, FL 32611 USA

[2] Univ Florida, Ctr Macromol Sci & Engn, Gainesville, FL 32611 USA

来源：

INORGANIC CHEMISTRY | 2003年 / 42卷 / 16期

关键词：

D O I：

10.1021/ic034217g

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The synthesis, characterization, and single crystal X-ray diffraction structures of a series of monoporphyrinate, trivalent lanthanide complexes with the monoanionic ligands hydridotris(1-pyrazolyl)borate (Tp) and (cyclopentadienyl)tris(diethylphosphinito)cobaltate (L(OEt)) having the general formulas M(TPP)(L) (M = Yb, Tm, Er, Ho, Nd, Pr; TPP = 5,10,15,20-tetraphenylporphyrinate; L = Tp, L(OEt)) are described. The photophysical properties of these complexes are also presented including their absorption, emission, and transient absorption properties.

引用

页码：5023 / 5032

页数：10

共 65 条

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