Dipole reversal in Langmuir-Blodgett films of an optically nonlinear dye and its effect on the polarity for molecular rectification

被引：31

作者：

Ashwell, GJ ^{[1
]}

Robinson, BJ

Amiri, MA

Locatelli, D

Quici, S

Roberto, D

机构：

[1] Cranfield Univ, Nanomat Grp, Cranfield MK43 0AL, Beds, England

[2] Univ Milan, Dipartimento Chim Inorgan Metallorgan & Anali, I-20133 Milan, Italy

[3] INSTM, UdR, I-20133 Milan, Italy

[4] CIMAINA, Ctr Eccellenza, I-20133 Milan, Italy

[5] CNR, Ist Sci & Tecnol Mol, Cranfield MK43 0AL, Beds, England

来源：

JOURNAL OF MATERIALS CHEMISTRY | 2005年 / 15卷 / 39期

关键词：

D O I：

10.1039/b506765k

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Langmuir - Blodgett (LB) films of isomeric donor - (pi-bridge) - acceptor molecules with either a hydrophobically substituted acceptor [D-pi-A-C16H33 ( 1)] or donor [A-pi-D-C16H33 ( 2)] exhibit second-harmonic generation and asymmetric current voltage characteristics: a reversed polarity for rectification arises from an inversion of the dipole orientations in the two types of monolayer.

引用

页码：4203 / 4205

页数：3

共 27 条

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