Electrochemical characteristics of Na/FeS2 battery by mechanical alloying

被引:58
作者
Kim, T. B. [3 ,5 ]
Jung, W. H. [4 ]
Ryu, H. S. [1 ,2 ]
Kim, K. W. [1 ,2 ]
Ahn, J. H. [5 ]
Cho, K. K. [1 ,2 ]
Cho, G. B. [1 ,2 ]
Nam, T. H. [1 ,2 ]
Ahn, I. S. [1 ,2 ]
Ahn, H. J. [1 ,2 ]
机构
[1] Gyeongsang Natl Univ, Sch Nano & Adv Mat Engn, Jinju 660701, Gyeongnam, South Korea
[2] Gyeongsang Natl Univ, Global Leader Dev Ctr Icube Mat & Parts, Jinju 660701, Gyeongnam, South Korea
[3] Saka Univ, Grad Sch Engn, Div Mat & Mfg Sci, Osaka, Japan
[4] Kaya AMA Co Ltd, Yangsan 626862, Gyeongnam, South Korea
[5] Gyeongsang Natl Univ, Dept Biol & Chem Engn, Jinju 660701, Gyeongnam, South Korea
关键词
sodium/iron disulfide battery; sodium battery; mechanical alloying;
D O I
10.1016/j.jallcom.2006.02.113
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
To develop the battery with low cost and high energy density, Na/FeS2 battery was prepared using FeS2 powder synthesized by mechanical alloying. With increasing the milling time from 20 to 60 h, the size of FeS2 powder decreased from 0.85 to 0.55 mu m. The discharge capacity of Na/FeS2 battery depended on the synthesizing condition of FeS2 powder. The FeS2 electrode prepared by 30h milling showed the highest discharge capacity of 447 mAh g(-1) -FeS2. The discharge capacity decreased continuously by repeated charge-discharge cycling, and remained 70 mAh g(-1)-FeS2 after 50th cycles. The Na/FeS2 cell could be used as a rechargeable battery at room temperature. (c) 2006 Elsevier B.V. All rights reserved.
引用
收藏
页码:304 / 307
页数:4
相关论文
共 10 条
[1]  
BAKER SC, 1990, SOLID STATE IONICS, V42, P109
[2]   Development of a lead-acid battery for a hybrid electric vehicle [J].
Cooper, A .
JOURNAL OF POWER SOURCES, 2004, 133 (01) :116-125
[3]   ZEBRA battery meets USABC goals [J].
Dustmann, CH .
JOURNAL OF POWER SOURCES, 1998, 72 (01) :27-31
[4]  
EICHINGER G, 1974, J ELECTROANAL CHEM, V58, P369
[5]   Electrochemical evaluation of sintered metal hydride electrodes for electric vehicle applications [J].
Jiang, JJ ;
Gasik, M ;
Laine, J ;
Lampinen, M .
JOURNAL OF ALLOYS AND COMPOUNDS, 2001, 322 (1-2) :281-285
[6]  
JUNG WH, 2005, J KOREAN POWDER META, V12, P179
[7]   Development of a bipolar Li/composite polymer electrolyte/pyrite battery for electric vehicles [J].
Livshits, V ;
Blum, A ;
Strauss, E ;
Ardel, G ;
Golodnitsky, D ;
Peled, E .
JOURNAL OF POWER SOURCES, 2001, 97-8 :782-785
[8]   Development of fast kinetics metal hydride alloys and battery electrodes for high power applications [J].
Otto, A ;
Güther, V .
JOURNAL OF ALLOYS AND COMPOUNDS, 1999, 293 :734-736
[9]   Self-discharge of lithium-sulfur cells using stainless-steel current-collectors [J].
Ryu, HS ;
Ahn, HJ ;
Kim, KW ;
Ahn, JH ;
Lee, JY ;
Cairns, EJ .
JOURNAL OF POWER SOURCES, 2005, 140 (02) :365-369
[10]   To the electrochemistry of pyrite in Li/solid composite-polymer-electrolyte battery [J].
Strauss, E ;
Golodnitsky, D ;
Freedman, K ;
Milner, A ;
Peled, E .
JOURNAL OF POWER SOURCES, 2003, 115 (02) :323-331