Fast lithium ion conduction in garnet-type Li7La3Zr2O12

被引：2630

作者：

Murugan, Ramaswamy

Thangadurai, Venkataraman

Weppner, Werner

机构：

[1] Univ Kiel, Fac Engn, Chair Sensors & Solid State Ion, D-24143 Kiel, Germany

[2] Univ Calgary, Dept Chem, Calgary, AB T2N 1N4, Canada

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2007年 / 46卷 / 41期

关键词：

electrochemistry; garnet; ionic conduction; lithium batteries; solid electrolytes;

D O I：

10.1002/anie.200701144

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

(Figure Presented) Low activation energy and fast lithium ion conduction have been observed for the new compound Li7La3Zr 2O12. Relative to previously reported lithium garnets, the solid electrolyte shows a larger cubic lattice constant, higher lithium ion concentration, lower degree of chemical interaction between the Li+ ions and the other lattice constituents, and higher densification. © 2007 Wiley-VCH Verlag GmbH & Co. KGaA.

引用

收藏

页码：7778 / 7781

页数：4

相关论文

共 33 条

[1] Fast Li-circle plus conducting ceramic electrolytes [J].

Adachi, GY ;

Imanaka, N ;

Aono, H .

ADVANCED MATERIALS, 1996, 8 (02) :127-+

[2] HIGH LI+ CONDUCTING CERAMICS [J].

AONO, H ;

IMANAKA, N ;

ADACHI, G .

ACCOUNTS OF CHEMICAL RESEARCH, 1994, 27 (09) :265-270

[3] Electrolytic stability limit and rapid lithium insertion in the fast-ion-conducting Li0.29La0.57TiO3 perovskite-type compound [J].

Birke, P ;

Scharner, S ;

Huggins, RA ;

Weppner, W .

JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1997, 144 (06) :L167-L169

[4] Mechanism of ionic conduction and electrochemical intercalation of lithium into the perovskite lanthanum lithium titanate [J].

Bohnke, O ;

Bohnke, C ;

Fourquet, JL .

SOLID STATE IONICS, 1996, 91 (1-2) :21-31

[5]

BOUKAMP BA, 1989, CT88265128CT89214128

[6] PREPARATION, STRUCTURAL CHARACTERIZATION AND CONDUCTIVITY OF LIZR2(PO4)3 [J].

CASCIOLA, M ;

COSTANTINO, U ;

MERLINI, L ;

ANDERSEN, IGK ;

ANDERSEN, EK .

SOLID STATE IONICS, 1988, 26 (03) :229-235

[7] The structure of lithium garnets:: cation disorder and clustering in a new family of fast Li+ conductors [J].

Cussen, EJ .

CHEMICAL COMMUNICATIONS, 2006, (04) :412-413

[8]

HELLSTROM EE, 1980, REV CHIM MINER, V17, P263

[9] CRYSTAL-STRUCTURE AND IONIC-CONDUCTIVITY OF LI14ZN(GEO4)4 AND OTHER NEW LI+ SUPERIONIC CONDUCTORS [J].

HONG, HYP .

MATERIALS RESEARCH BULLETIN, 1978, 13 (02) :117-124

[10] IONIC-CONDUCTIVITY OF LITHIUM ORTHOSILICATE - LITHIUM PHOSPHATE SOLID-SOLUTIONS [J].

HU, YW ;

RAISTRICK, ID ;

HUGGINS, RA .

JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1977, 124 (08) :1240-1242

← 1 2 3 4 →