Synthesis and properties of an iron hydrogenase active site model linked to a ruthenium tris-bipyridine photosensitizer

被引：53

作者：

Wolpher, H

Borgström, M

Hammarström, L

Bergquist, J

Sundström, V

Stenbjörn, S

Sun, LC ^{[1
]}

Åkermark, B

机构：

[1] Univ Stockholm, Arrhenius Lab, Dept Organ Chem, S-10691 Stockholm, Sweden

[2] Univ Uppsala, BMC, Dept Phys Chem, S-75123 Uppsala, Sweden

[3] Uppsala Univ, Dept Analyt Chem, S-75124 Uppsala, Sweden

[4] Lund Univ, Ctr Chem & Chem Engn, Dept Chem Phys, S-22100 Lund, Sweden

[5] Lund Univ, Ctr Chem & Chem Engn, Dept Biochem, S-22100 Lund, Sweden

来源：

INORGANIC CHEMISTRY COMMUNICATIONS | 2003年 / 6卷 / 08期

关键词：

iron hydrogenase; biomimetic model; dinuclear iron complex; ruthenium tris-bipyridine; photosensitizer;

D O I：

10.1016/S1387-7003(03)00140-0

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A dinuclear iron complex, related to the active site of Fe hydrogenases, has been covalently linked to a redox active ruthenium tris-bipyridine type photosensitizer. Photophysics and electrochemistry of this system are studied in solution. IR spectra of this complex together with its precursor, the dinuclear iron complex, were also shown. (C) 2003 Elsevier Science B.V. All rights reserved.

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页码：989 / 991

页数：3

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