Formation of an α-ketocarbene by photolysis of aqueous 2-bromophenol

被引：37

作者：

Bonnichon, F

Richard, C ^{[1
]}

Grabner, G

机构：

[1] Univ Blaise Pascal, Photochim Mol & Macromol Lab, UMR 6505, F-63177 Clermont Ferrand, France

[2] Univ Vienna, Inst Theoret Chem & Mol Strukturbiol, A-1090 Vienna, Austria

来源：

CHEMICAL COMMUNICATIONS | 2001年 / 01期

关键词：

D O I：

10.1039/b006155g

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The alpha -ketocarbene 2-oxocyclohexa-3,5-dienylidene (lambda (max) = 360, 375 and 388 nm) is detected upon laser flash photolysis of 2-bromophenol in aqueous solution; its formation is confirmed by photoproduct studies.

引用

页码：73 / 74

页数：2

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