Femtosecond absorption spectroscopy of transition metal charge-transfer complexes

被引：368

作者：

McCusker, JK ^{[1
]}

机构：

[1] Michigan State Univ, Dept Chem, E Lansing, MI 48824 USA

来源：

ACCOUNTS OF CHEMICAL RESEARCH | 2003年 / 36卷 / 12期

关键词：

D O I：

10.1021/ar030111d

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Our research is concerned with the application of femtosecond time-resolved absorption techniques to the study of the photophysics of transition metal complexes. The focus is to understand the events that characterize the process of excited-state evolution from the time a photon is absorbed by a molecule to the formation of the lowest-energy excited state of the system. This Account describes our initial observations in this area and includes examples detailing these dynamics as they occur in the charge-transfer excited states of transition-metal polypyridyl chromophores.

引用

页码：876 / 887

页数：12

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