Determination of nickel by a new chromogenic azocalix[4]arene

被引：61

作者：

Ma, QL ^{[1
]}

Ma, HM ^{[1
]}

Su, MH ^{[1
]}

Wang, ZH ^{[1
]}

Nie, LH ^{[1
]}

Liang, SC ^{[1
]}

机构：

[1] Chinese Acad Sci, Inst Chem, Ctr Mol Sci, Beijing 100080, Peoples R China

来源：

ANALYTICA CHIMICA ACTA | 2001年 / 439卷 / 01期

基金：

中国国家自然科学基金;

关键词：

chromoionophore; calixarene; nickel; spectrophotometry;

D O I：

10.1016/S0003-2670(01)01009-1

中图分类号：

O65 [分析化学];

学科分类号：

070302 ; 081704 ;

摘要：

A novel azocalix[4]arene, 5,17-bis (quinolyl-8-azo)-25,26,27,28 -tetrahydroxycalix [4] arene 1, was prepared by linking 8-aminoquinoline to calix[4]arene through a diazo-coupling reaction. Based on it, a simple, sensitive and selective spectrophotometric method was developed for the determination of Ni2+. In basic media, Ni2+ formed a 1:1 complex with 1. Beer's law was obeyed in the range 1.7 x 10(-7)-5.1 x 10(-6) mol l(-1) of Ni2+. The apparent molar absorptivity (epsilon) of 1-Ni2+ complex was 1.28 x 10(5) 1mol(-1) cm(-1) at 580 nm, and the detection limit was 1.4 x 10(-7) mol l(-1) (S/N = 3). The relative standard deviation for measurement of 8.5 x 10(-7) mol l(-1) Ni2+ was 2.7% (n = 10). The proposed method was applied to the determination of trace amount of Ni2+ in certified samples with satisfactory results. (C) 2001 Elsevier Science B.V. All rights reserved.

引用

页码：73 / 79

页数：7

共 28 条

[1] CALIXARENES, MACROCYCLES WITH (ALMOST) UNLIMITED POSSIBILITIES [J].

BOHMER, V .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1995, 34 (07) :713-745

[2]

Chen CF, 1998, CHINESE CHEM LETT, V9, P993

[3]

CHTO K, 1999, ANAL CHIM ACTA, V387, P61

[4] Synthesis of 2-[2-(5-methylbenzothiazolyl)azo]-5-dimethylaminobenzoic acid and its application to the spectrophotometric determination of nickel [J].

Fan, XZ ;

Zhang, GF ;

Zhu, CH .

ANALYST, 1998, 123 (01) :109-112

[5]

FENG J, 1992, CHINESE J ANAL CHEM, V20, P1188

[6] Molecular baskets in supercritical CO2 [J].

Glennon, JD ;

Hutchinson, S ;

Harris, SJ ;

Walker, A ;

McKervey, MA ;

McSweeney, CC .

ANALYTICAL CHEMISTRY, 1997, 69 (11) :2207-2212

[7] A CALIXARENE-BASED CHROMOIONOPHORE FOR THE LARGER ALKALI-METALS [J].

GORDON, JLM ;

BOHMER, V ;

VOGT, W .

TETRAHEDRON LETTERS, 1995, 36 (14) :2445-2448

[8] SELECTIVE SPECTROPHOTOMETRIC DETERMINATION OF NICKEL IN HYDROGENATED GREASES, STEELS AND SOLDERS BY SOLVENT-EXTRACTION WITH 3-(4-METHOXYPHENYL)-2-MERCAPTOPROPENOIC ACID [J].

IZQUIERDO, A ;

CARRASCO, J .

ANALYST, 1984, 109 (05) :605-609

[9] ARSENAZOIII AS AN INDICATOR FOR IONIZED CALCIUM IN PHYSIOLOGICAL SALT-SOLUTIONS - ITS USE FOR DETERMINATION OF CAATP DISSOCIATION-CONSTANT [J].

KENDRICK, NC ;

RATZLAFF, RW ;

BLAUSTEIN, MP .

ANALYTICAL BIOCHEMISTRY, 1977, 83 (02) :433-450

[10] Cesium-ion selective electrodes based on calix[4]arene dibenzocrown ethers [J].

Kim, JS ;

Ohki, A ;

Ueki, R ;

Ishizuka, T ;

Shimotashiro, T ;

Maeda, S .

TALANTA, 1999, 48 (03) :705-710

← 1 2 3 →