Amperometric detection of electroinactive anions using conducting polymer electrodes subsequent to chromatographic separation

被引：24

作者：

Barisci, JN ^{[1
]}

Wallace, GG ^{[1
]}

Clarke, A ^{[1
]}

机构：

[1] DIONEX CHEM CORP,SUNNYVALE,CA 94088

来源：

ELECTROANALYSIS | 1997年 / 9卷 / 06期

关键词：

amperometric detection of electroinactive anions; chloride-containing polypyrrole electrode; ion chromatography;

D O I：

10.1002/elan.1140090606

中图分类号：

O65 [分析化学];

学科分类号：

070302 ; 081704 ;

摘要：

The use of a chloride-containing polypyrrole electrode for the amperometric detection of electroinactive anions subsequent to separation by ion chromatography in suppressed, low conductivity eluent is described. It is demonstrated that changes in selectivity can be obtained by the application of different potential waveforms and current sampling protocols. The approach described is based on the anion dependence of the oxidation/reduction kinetics of the conducting polymer film induced by the applied potential.

引用

页码：461 / 467

页数：7

共 10 条

[1] Studies of the preparation and analytical application of polypyrrole-coated microelectrodes for determination of aluminum [J].