The first example of an anion-pyrrole complex

被引：8

作者：

Coles, SJ ^{[1
]}

Gale, PA ^{[1
]}

Hursthouse, MB ^{[1
]}

机构：

[1] Univ Southampton, Dept Chem, Southampton SO17 1BJ, Hants, England

来源：

CRYSTENGCOMM | 2001年 / 53期

关键词：

D O I：

10.1039/b109813f

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Tetramethylammonium chloride (1) has been recrystallized from pyrrole (2) yielding a pyrrole-chloride complex (I) that has been crystallographically characterized. Complex I contains a chloride anion that is bound by hydrogen bonds from two pyrrole rings and a tetramethylammonium cation. The supramolecular structure is reminiscent of a honeycomb array, comprised of a pyrrole-chloride framework with cavities occupied by tetramethylammonium moities.

引用

页数：3

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