Field emission from aligned carbon nanotubes prepared by thermal chemical vapor deposition of Fe-phthalocyanine

被引:47
作者
Araki, H [1 ]
Katayama, T [1 ]
Yoshino, K [1 ]
机构
[1] Osaka Univ, Grad Sch Engn, Dept Elect Engn, Suita, Osaka 5650871, Japan
关键词
D O I
10.1063/1.1410874
中图分类号
O59 [应用物理学];
学科分类号
摘要
The field emission from aligned multiwalled carbon nanotubes prepared by thermal chemical vapor deposition of Fe-phthalocyanine is reported, with emphasis on the current-voltage characteristics and current fluctuation. By running of a pristine emitter at high current and/or voltage for a long time, the onset voltage is lowered from 400 to 125 V and the field-enhancement factor increases from 360 to 1110, demonstrating geometrical reconstruction of the nanotube apex. Deviation from the Fowler-Nordheim relation is caused at a constant local electric field of similar to 4x10(3) V/mum and is related to high-field conditioning. Electron emission current under a high current density condition (> 10 mA/cm2) is stable and noiseless. The reason for current noise in the lower current density is discussed. (C) 2001 American Institute of Physics.
引用
收藏
页码:2636 / 2638
页数:3
相关论文
共 18 条
[1]   Effects of substrate materials on growth of carbon nanotubes by chemical vapor deposition using metal-phthalocyanines [J].
Araki, H ;
Kajii, H ;
Yoshino, K .
JAPANESE JOURNAL OF APPLIED PHYSICS PART 2-LETTERS, 1999, 38 (11B) :L1351-L1353
[2]   Growth of carbon nanotubes on quartz plates by chemical vapor deposition using (Ni, Fe)- phthalocyanines [J].
Araki, H ;
Kajii, H ;
Yoshino, K .
JAPANESE JOURNAL OF APPLIED PHYSICS PART 2-LETTERS, 1999, 38 (7B) :L836-L838
[3]   SPACE-CHARGE EFFECTS IN FIELD EMISSION [J].
BARBOUR, JP ;
DOLAN, WW ;
TROLAN, JK ;
MARTIN, EE ;
DYKE, WP .
PHYSICAL REVIEW, 1953, 92 (01) :45-51
[4]   Field emission from single-wall carbon nanotube films [J].
Bonard, JM ;
Salvetat, JP ;
Stockli, T ;
de Heer, WA ;
Forro, L ;
Chatelain, A .
APPLIED PHYSICS LETTERS, 1998, 73 (07) :918-920
[5]   Electronic structure and localized states at carbon nanotube tips [J].
Carroll, DL ;
Redlich, P ;
Ajayan, PM ;
Charlier, JC ;
Blase, X ;
DeVita, A ;
Car, R .
PHYSICAL REVIEW LETTERS, 1997, 78 (14) :2811-2814
[6]   Field emission of different oriented carbon nanotubes [J].
Chen, Y ;
Shaw, DT ;
Guo, LP .
APPLIED PHYSICS LETTERS, 2000, 76 (17) :2469-2471
[7]   Unique characteristics of cold cathode carbon-nanotube-matrix field emitters [J].
Collins, PG ;
Zettl, A .
PHYSICAL REVIEW B, 1997, 55 (15) :9391-9399
[8]   Three behavioral states observed in field emission from single-walled carbon nanotubes [J].
Dean, KA ;
von Allmen, P ;
Chalamala, BR .
JOURNAL OF VACUUM SCIENCE & TECHNOLOGY B, 1999, 17 (05) :1959-1969
[9]   Field emission microscopy of carbon nanotube caps [J].
Dean, KA ;
Chalamala, BR .
JOURNAL OF APPLIED PHYSICS, 1999, 85 (07) :3832-3836
[10]   A CARBON NANOTUBE FIELD-EMISSION ELECTRON SOURCE [J].
DEHEER, WA ;
CHATELAIN, A ;
UGARTE, D .
SCIENCE, 1995, 270 (5239) :1179-1180