The Curtin-Hammett principle: Stereoselective radical additions to alkenes

被引：32

作者：

Roth, M ^{[1
]}

Damm, W ^{[1
]}

Giese, B ^{[1
]}

机构：

[1] UNIV BASEL,DEPT CHEM,CH-4056 BASEL,SWITZERLAND

来源：

TETRAHEDRON LETTERS | 1996年 / 37卷 / 03期

关键词：

D O I：

10.1016/0040-4039(95)02153-1

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The more stable ''A-strain'' conformer 4A of alkene 4 (L = Bu(1)) reacts much slower with alkyl radicals than the less stable ''Felkin-Anh'' conformer 4B. This leads to anti-isomer 6 as the main product if the attacking radical is bulky.

引用

页码：351 / 354

页数：4

共 7 条

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