Thermal degradation of halogen-free flame retardant epoxides and polycarbonate in air

被引：58

作者：

Becker, L ^{[1
]}

Lenoir, D ^{[1
]}

Matuschek, G ^{[1
]}

Kettrup, A ^{[1
]}

机构：

[1] GSF Forschungszentrum Umwelt & Gesundheit, Inst Okol Chem, D-85758 Neuherberg, Germany

来源：

JOURNAL OF ANALYTICAL AND APPLIED PYROLYSIS | 2001年 / 60卷 / 01期

关键词：

thermal degradation; halogen-free flame retardants; epoxides; polycarbonate;

D O I：

10.1016/S0165-2370(00)00118-2

中图分类号：

O65 [分析化学];

学科分类号：

070302 ; 081704 ;

摘要：

The thermolysis products in air of two new epoxide based halogen-free flame retardant thermosetting plastics and polycarbonate, a commonly used thermoplastic with some structural similarity to the thermosets, are reported. The thermolysis was carried out in a VCI combustion apparatus at 400, 600 and 800 degreesC and an air flow rate of 100 ml min(-1). The emission products from the VCI-apparatus were analysed qualitatively and quantitatively by gas chromatography coupled with a mass selective detector (GC/MSD). A mechanistic scheme for the formation of thermal degradation products is presented. (C) 2001 Elsevier Science B.V. All rights reserved.

引用

页码：55 / 67

页数：13

共 30 条

[1] ASHIDA K, 1974, J CELL PLAST JUL, P181
[2] THERMAL-BEHAVIOR OF MONO-2-OXAZOLIDINONES, BIS-2-OXAZOLIDINONES AND POLY-2-OXAZOLIDINONES
BALD, G
KRETZSCHMAR, K
MARKERT, H
WIMMER, M
[J]. ANGEWANDTE MAKROMOLEKULARE CHEMIE, 1975, 44 (MAY5): : 151 - 163
[3] BECKER L, 1997, THESIS TUM WEIHENSTE
[4] FORMATION MECHANISMS OF AROMATIC-COMPOUNDS IN ALIPHATIC FLAMES
COLE, JA
BITTNER, JD
LONGWELL, JP
HOWARD, JB
[J]. COMBUSTION AND FLAME, 1984, 56 (01) : 51 - 70
[5] SIMULTANEOUS THERMAL-ANALYSIS MASS-SPECTROMETRY AND OFF-LINE COMBUSTION-GAS CHROMATOGRAPHY EXPERIMENTS OF NEW DUROPLASTIC MATERIALS WITHOUT HALOGEN AS FLAME RETARDANTS
CYRYS, J
LENOIR, D
MATUSCHEK, G
KETTRUP, A
[J]. JOURNAL OF ANALYTICAL AND APPLIED PYROLYSIS, 1995, 34 (02) : 157 - 172
[6] CYRYS J, 1994, FLAM RETARDANCY POLY, V5, P383
[7] *DIN, 1991, 32645 DIN
[8] FISCHER G, 1990, ORG CHEM INGENIEURE
[9] DEGRADATION OF EPOXY POLYMERS .2. MECHANISM OF THERMAL-DEGRADATION OF BISPHENOL-A DIGLYCIDYL ETHER
GRASSIE, N
GUY, MI
TENNENT, NH
[J]. POLYMER DEGRADATION AND STABILITY, 1985, 13 (01) : 11 - 20
[10] ANALYSIS AND TOXICITY TESTING OF COMBUSTION GASES .2. CHARACTERIZATION OF COMBUSTION PRODUCTS FROM HALOGEN-FREE FLAME-RETARDANT DUROPLASTIC POLYMERS FOR ELECTRONICS
HAUK, A
SKLORZ, M
BERGMANN, G
HUTZINGER, O
[J]. JOURNAL OF ANALYTICAL AND APPLIED PYROLYSIS, 1995, 31 : 141 - 156

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