Unusual molybdenum mediated C-N bond activation

被引：42

作者：

Cameron, TM

Abboud, KA

Boncella, JM ^{[1
]}

机构：

[1] Univ Florida, Dept Chem, Gainesville, FL 32611 USA

[2] Univ Florida, Ctr Catalysis, Gainesville, FL 32611 USA

来源：

CHEMICAL COMMUNICATIONS | 2001年 / 13期

关键词：

D O I：

10.1039/b101894i

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The compounds [Mo(NPh)(eta (2)-olefin){o-(Me3SiN)(2)C6H4}] (olefin = propene 1a or isobutene 1b) react with excess pyridine affording the Mo(iv) bis-pyridine complex, [Mo(NPh)(Py)(2){o-(Me3SiN)(2)C6H4}] 2 which when heated to 90 degreesC in toluene undergoes a C-N bond cleavage reaction and is converted to 3, a bimetallic molybdenum species; the crystal structures of both 2 and 3 are reported.

引用

页码：1224 / +

页数：2

共 26 条

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