Alternating copolymerization of cyclohexene oxide and CO2 catalyzed by zinc complexes with new 3-amino-2-cyanoimidoacrylate ligands

被引：50

作者：

Kröger, M ^{[1
]}

Folli, C ^{[1
]}

Walter, O ^{[1
]}

Döring, M ^{[1
]}

机构：

[1] Forschungszentrum Karlsruhe, ITC, CPV, D-76344 Eggenstein Peopoldshafen, Germany

来源：

ADVANCED SYNTHESIS & CATALYSIS | 2005年 / 347卷 / 10期

关键词：

carbon dioxide fixation; copolymerization; green chemistry; homogeneous catalysis; ligand design;

D O I：

10.1002/adsc.200505113

中图分类号：

O69 [应用化学];

学科分类号：

081704 ;

摘要：

New 3-amino-2-cyanoimidoacrylate ligands with varying steric demands have been synthesized. Zinc acetate complexes of these ligands catalyze the copolymerisation Of CO2 and cyclohexene oxide, showing high activities (TOF up to over 200 h (-1)).

引用

页码：1325 / 1328

页数：4

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