(Pro2H+)2(TCNQ•-)2•TCNQ: An Amino Acid Derived Semiconductor

被引：35

作者：

Qu, Xiaohu ^{[1
]}

Lu, Jinzhen ^{[1
]}

Zhao, Chuan ^{[1
]}

Boas, John F. ^{[2
]}

Moubaraki, Boujemaa ^{[1
]}

Murray, Keith S. ^{[1
]}

Siriwardana, Amal ^{[1
]}

Bond, Alan M. ^{[1
]}

Martin, Lisandra L. ^{[1
]}

机构：

[1] Monash Univ, Sch Chem, Clayton, Vic 3800, Australia

[2] Monash Univ, Sch Phys, Clayton, Vic 3800, Australia

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2011年 / 50卷 / 07期

基金：

澳大利亚研究理事会;

关键词：

amino acids; biomaterials; proline; semiconductors; tetracyanoquinodimethane; SCANNING-TUNNELING-MICROSCOPY; ANION-RADICAL DERIVATIVES; TTF-TCNQ; DENSITY WAVES; THIN-FILMS; TETRACYANOQUINODIMETHANE; 7,7,8,8-TETRACYANOQUINODIMETHANE; FABRICATION; COMPLEXES; MICROCRYSTALS;

D O I：

10.1002/anie.201005406

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

An attractive couple: (Pro2H+)2(TCNQ .-)2 · TCNQ (TCNQ=tetracyanoquinodimethane) contains an H-bonding network that supports a layered structure, composed of alternating TCNQ anions and proline cations (see picture). The cation is formed by two zwitterionic proline amino acids supported by a proton bridge between the carboxylates, whereas the anionic component involves a neutral TCNQ molecule sandwiched between two TCNQ.-. © 2011 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

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收藏

页码：1589 / 1592

页数：4

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