Synthesis of new element-substituted derivatives of 3H-pyrrolizines

被引：5

作者：

Kissounko, DA ^{[1
]}

Kissounko, NS

Krut'ko, DP

Brusova, GP

Lemenovskii, DA

Boag, NM

机构：

[1] Moscow MV Lomonosov State Univ, Dept Chem, Moscow 119899, Russia

[2] Univ Salford, Dept Chem & Appl Chem, Salford M5 4WT, Lancs, England

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1998年 / 556卷 / 1-2期

基金：

俄罗斯基础研究基金会;

关键词：

3H-pyrrolizine; silicon; tin; lithium; thallium;

D O I：

10.1016/S0022-328X(97)00771-7

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The anion of 3H-pyrrolizine was isolated as its lithium 2a and thallium salts 3 and the anion of 1-methyl-3H-pyrrolizine as its lithium salt 2b. Reaction of the lithium anions with Group 14 electrophiles led to a number of substituted derivatives of the 3H-pyrrolizine ring system. In the case of 2b it was shown that the number of isomers obtained was strongly dependent on the reaction solvent. (C) 1998 Elsevier Science S.A. All rights reserved.

引用

页码：145 / 149

页数：5

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