Radical-chain reductive carboxyalkylation of electron-rich alkenes: carbon-carbon bond formation mediated by silanes in the presence of thiols as polarity-reversal catalysts

被引：22

作者：

Dang, HS ^{[1
]}

Kim, KM ^{[1
]}

Roberts, BP ^{[1
]}

机构：

[1] Univ London Univ Coll, Dept Chem, Christopher Ingold Labs, London WC1H 0AJ, England

来源：

CHEMICAL COMMUNICATIONS | 1998年 / 13期

关键词：

D O I：

10.1039/a802826e

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The reductive carboxyalkylation of electron-rich alkenes by alpha-halogenoesters in the presence of triphenylsilane under Free-radical conditions is catalysed by thiols: prochiral alkenes give optically-active adducts when the thiol catalyst is homochiral.

引用

页码：1413 / 1414

页数：2

共 18 条

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