Highly efficient and thermally stable electro-optic polymer from a smartly controlled crosslinking process

被引：63

作者：

Luo, JD ^{[1
]}

Haller, M ^{[1
]}

Li, HX ^{[1
]}

Kim, TD ^{[1
]}

Jen, AKY ^{[1
]}

机构：

[1] Univ Washington, Dept Mat Sci & Engn, Seattle, WA 98195 USA

来源：

ADVANCED MATERIALS | 2003年 / 15卷 / 19期

关键词：

D O I：

10.1002/adma.200305202

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A nonlinear optical polymer, which is thermo-reversibly crosslinkable (see Figure), has been developed to overcome the nonlinearity-stability trade-off in poled polymers. High poling efficiency has been achieved after controlled, mild lattice hardening via the Diels-Alder crosslinking reaction. The resulting material exhibits a large electro-optic coefficient (r(33)=76 pmV(-1) at 1.3 mum) and excellent temporal stability.

引用

页码：1635 / +

页数：5

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