Modelling NiFe hydrogenases: nickel-based electrocatalysts for hydrogen production

被引：133

作者：

Canaguier, Sigolene ^{[1
]}

Artero, Vincent ^{[1
]}

Fontecave, Marc ^{[1
]}

机构：

[1] Univ Grenoble 1, CNRS, UMR 5249, Lab Chim Biol Metaux,CEA,DSV iRTSV, F-38054 Grenoble 9, France

来源：

DALTON TRANSACTIONS | 2008年 / 03期

关键词：

D O I：

10.1039/b713567j

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

NiFe hydrogenases are unique enzymes that catalyze the H+/H-2 interconversion with remarkable efficiency. The determination of the tridimensional structure of their active site (a sulfur-rich dinuclear nickel-iron cluster with diatomic cyanide and carbonyl ligands) has stimulated the synthesis of a variety of nickel-based complexes as potential electrocatalysts for hydrogen production. These catalysts may provide an adequate alternative to platinum. This paper gives an historical perspective of this biomimetic structural approach and then focusses on recently reported bio-inspired functional mimics displaying electrocatalytic activity for hydrogen production.

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页码：315 / 325

页数：11

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