Selective Formation of Imines by Aerobic Photocatalytic Oxidation of Amines on TiO2

被引：402

作者：

Lang, Xianjun ^{[1
]}

Ji, Hongwei ^{[1
]}

Chen, Chuncheng ^{[1
]}

Ma, Wanhong ^{[1
]}

Zhao, Jincai ^{[1
]}

机构：

[1] Chinese Acad Sci, Key Lab Photochem, Beijing Natl Lab Mol Sci, Inst Chem, Beijing 100190, Peoples R China

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2011年 / 50卷 / 17期

关键词：

imines; photocatalysis; selective oxidation; titanium dioxide; MONOAMINE-OXIDASE CATALYSIS; HETEROGENEOUS PHOTOCATALYSIS; BENZYLIC AMINES; SUPPORTED GOLD; ONE-POT; ALCOHOLS; DEHYDROGENATION; PHOTOOXIDATION; NANOPARTICLES; CYCLOHEXANE;

D O I：

10.1002/anie.201007056

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

An oxygenation pathway: The title transformation involves a two-step process: a selective oxygenation step to generate aldehyde intermediates and a subsequent condensation step to afford the imine products (see scheme). © 2011 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

引用

页码：3934 / 3937

页数：4

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