1J(199Hg199Hg) values of up to 284 kHz in complexes of [Hg-Hg]2+ with crown ethers:: the largest indirect coupling constants

被引：26

作者：

Malleier, R ^{[1
]}

Kopacka, H ^{[1
]}

Schuh, W ^{[1
]}

Wurst, K ^{[1
]}

Peringer, P ^{[1
]}

机构：

[1] Univ Innsbruck, Inst Allgemeine Anorgan & Theoret Chem, A-6020 Innsbruck, Austria

来源：

CHEMICAL COMMUNICATIONS | 2001年 / 01期

关键词：

D O I：

10.1039/b007581g

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The values of the (1)J((HgHg)-Hg-199-Hg-199) coupling constant in solution of the asymmetric dimercury(2+) complexes with the stoichiometries Hg-2(2+)/18-crown-6 and Hg-2(2+)/18-crown-6/15-crown-5 are 220 300 and 284 100 Hz, respectively, representing the largest scalar couplings measured.

引用

页码：51 / 52

页数：2

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