Synthesis of both enantiomers of 15-hexadecanolide, a sex pheromone component of the stink bug, Piezodorus hybneri

被引：7

作者：

Kuwahara, S ^{[1
]}

Tsuruta, T

Leal, WS

Kodama, O

机构：

[1] Ibaraki Univ, Fac Agr, Lab Agr Chem, Ami, Ibaraki 3000393, Japan

[2] Natl Inst Sericultural & Entomol Sci, Lab Chem Prospecting, Ibaraki, Osaka 3058634, Japan

来源：

BIOSCIENCE BIOTECHNOLOGY AND BIOCHEMISTRY | 1998年 / 62卷 / 06期

关键词：

15-hexadecanolide; sex pheromone; stink bug; Piezodorus hybneri; macrolactonization;

D O I：

10.1271/bbb.62.1261

中图分类号：

Q5 [生物化学]; Q7 [分子生物学];

学科分类号：

071010 ; 081704 ;

摘要：

Both enantiomers of 15-hexadecanolide, a sex pheromone component of the stink bug (Piezodorus hybneri), were synthesized by using the Yamaguchi or Mitsunobu macrolactonization reaction of (R)-15-hydroxyhexadecanoic acid prepared from ethyl (R)-beta-hydroxybutyrate in 5 steps.

引用

页码：1261 / 1263

页数：3

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