Recovery of lithium from seawater using manganese oxide adsorbent (H1.6Mn1.6O4) derived from Li1.6Mn1.6O4

被引:295
作者
Chitrakar, R [1 ]
Kanoh, H [1 ]
Miyai, Y [1 ]
Ooi, K [1 ]
机构
[1] Natl Inst Adv Ind Sci & Technol, Separat Technol Grp, Takamatsu, Kagawa 7610395, Japan
关键词
D O I
10.1021/ie000911h
中图分类号
TQ [化学工业];
学科分类号
0817 ;
摘要
Manganese oxide adsorbent (H1.6Mn1.6O4) was synthesized from precursor Li1.6Mn1.6O4 that was obtained by heating LiMnO2 at 400 degreesC. LiMnO2 was prepared by two methods: hydrothermal and reflux. The crystallite size of Li1.6Mn1.6O4 and its delithiated product; was slightly higher by the hydrothermal method as compared to the reflux method. The adsorbents prepared by the two methods were compared in terms of physical characteristics and lithium adsorption from seawater. The maximum uptake of lithium from seawater by the adsorbent was 40 mg/g, which is the maximum value among the adsorbents studied to date.
引用
收藏
页码:2054 / 2058
页数:5
相关论文
共 20 条
[1]   SYNTHETIC INORGANIC ION-EXCHANGE MATERIALS .45. RECOVERY OF LITHIUM FROM SEAWATER AND HYDROTHERMAL WATER BY TITANIUM(IV) ANTIMONATE CATION EXCHANGER [J].
ABE, M ;
CHITRAKAR, R .
HYDROMETALLURGY, 1987, 19 (01) :117-128
[2]   MECHANISM OF PROTON INSERTION AND CHARACTERIZATION OF THE PROTON SITES IN LITHIUM MANGANATE SPINELS [J].
AMMUNDSEN, B ;
JONES, DJ ;
ROZIERE, J ;
BURNS, GR .
CHEMISTRY OF MATERIALS, 1995, 7 (11) :2151-2160
[3]   A new type of manganese oxide (MnO2•0.5H2O) derived from Li1.6Mn1.6O4 and its lithium ion-sieve properties [J].
Chitrakar, R ;
Kanoh, H ;
Miyai, Y ;
Ooi, K .
CHEMISTRY OF MATERIALS, 2000, 12 (10) :3151-3157
[4]   Synthesis of spinel-type lithium antimony manganese oxides and their Li+ extraction/ion insertion reactions [J].
Chitrakar, R ;
Kanoh, H ;
Makita, Y ;
Miyai, Y ;
Ooi, K .
JOURNAL OF MATERIALS CHEMISTRY, 2000, 10 (10) :2325-2329
[5]  
Dang V.-D., 1978, Energy, V3, P325, DOI 10.1016/0360-5442(78)90029-4
[6]   EXTRACTION OF LITHIUM FROM THE DEAD-SEA [J].
EPSTEIN, JA ;
FEIST, EM ;
ZMORA, J ;
MARCUS, Y .
HYDROMETALLURGY, 1981, 6 (3-4) :269-275
[7]   LI+ EXTRACTION/INSERTION WITH SPINEL-TYPE LITHIUM MANGANESE OXIDES - CHARACTERIZATION OF REDOX-TYPE AND ION-EXCHANGE-TYPE SITES [J].
FENG, Q ;
MIYAI, Y ;
KANOH, H ;
OOI, K .
LANGMUIR, 1992, 8 (07) :1861-1867
[8]   AN INVESTIGATION OF SPINEL-RELATED AND ORTHORHOMBIC LIMNO2 CATHODES FOR RECHARGEABLE LITHIUM BATTERIES [J].
GUMMOW, RJ ;
THACKERAY, MM .
JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1994, 141 (05) :1178-1182
[9]  
Hartley J. N., 1978, Energy, V3, P337, DOI 10.1016/0360-5442(78)90030-0
[10]   PREPARATION OF A NEW CRYSTAL FORM OF MANGANESE-DIOXIDE - LAMBDA-MNO2 [J].
HUNTER, JC .
JOURNAL OF SOLID STATE CHEMISTRY, 1981, 39 (02) :142-147