Sonochemical synthesis under a magnetic field: Structuring magnetite nanoparticles and the destabilization of a colloidal magnetic aqueous solution under a magnetic field

被引:25
作者
Abu-Much, R. [1 ,2 ]
Gedanken, A. [1 ,2 ]
机构
[1] Bar Ilan Univ, Dept Chem, IL-52900 Ramat Gan, Israel
[2] Bar Ilan Univ, Kanbar Lab Nanomat, Bar Ilan Univ Ctr Adv Mat & Nanotechnol, IL-52900 Ramat Gan, Israel
关键词
D O I
10.1021/jp075637k
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
This work is devoted to the investigation of the effect of an external magnetic field (NIF) applied to a sonochemical synthesis. The paper presents results on the preparation of both aggregated magnetite nanoparticles and the destabilization of a magnetite hydrosol that is formed without a MF. The results reveal a difference in morphology, size, and magnetic properties of the product obtained under a MF. They also show that the applied magnetic field affects the stabilization mechanism of the magnetite particles in an aqueous solution and destroys the stable hydrosol formed without a NIF. Instead, the formation of tree-like, aggregated structures composed of small particles is observed.
引用
收藏
页码:35 / 42
页数:8
相关论文
共 64 条
[1]   Formation of a three-dimensional microstructure of Fe3O4-poly(vinyl alcohol) composite by evaporating the hydrosol under a magnetic field [J].
Abu-Much, R ;
Meridor, U ;
Frydman, A ;
Gedanken, A .
JOURNAL OF PHYSICAL CHEMISTRY B, 2006, 110 (16) :8194-8203
[2]   COMPLEX DYNAMICS OF MESOSCOPIC MAGNETS [J].
AWSCHALOM, DD ;
DIVINCENZO, DP .
PHYSICS TODAY, 1995, 48 (04) :43-48
[3]   IONIC FERROFLUIDS - A CROSSING OF CHEMISTRY AND PHYSICS [J].
BACRI, JC ;
PERZYNSKI, R ;
SALIN, D ;
CABUIL, V ;
MASSART, R .
JOURNAL OF MAGNETISM AND MAGNETIC MATERIALS, 1990, 85 (1-3) :27-32
[4]   Anomalous properties of magnetic nanoparticles [J].
Berkowitz, AE ;
Kodama, RH ;
Makhlouf, SA ;
Parker, FT ;
Spada, FE ;
McNiff, EJ ;
Foner, S .
JOURNAL OF MAGNETISM AND MAGNETIC MATERIALS, 1999, 196 :591-594
[5]  
BERRY C, 2003, J PHYS D, V36, pR182
[6]   Modulation of spacing and magnetic properties of iron oxide nanoparticles through polymer-mediated "bricks and mortar" self-assembly [J].
Boal, AK ;
Frankamp, BL ;
Uzun, O ;
Tuominen, MT ;
Rotello, VM .
CHEMISTRY OF MATERIALS, 2004, 16 (17) :3252-3256
[7]  
Bönnemann H, 2001, EUR J INORG CHEM, P2455
[8]   ENHANCED MAGNETIZATION OF NANOSCALE COLLOIDAL COBALT PARTICLES [J].
CHEN, JP ;
SORENSEN, CM ;
KLABUNDE, KJ ;
HADJIPANAYIS, GC .
PHYSICAL REVIEW B, 1995, 51 (17) :11527-11532
[9]   Resonant spin tunneling in small magnetic particles [J].
Chudnovsky, EM .
JOURNAL OF MAGNETISM AND MAGNETIC MATERIALS, 1998, 185 (03) :L267-L273
[10]  
CULLITY BD, 1972, INTRO MAGNETIC MAT, P616