Supercritical fluid technology of nanoparticle coating for new ceramic materials

被引:27
作者
Aymonier, C [1 ]
Elissalde, C [1 ]
Reveron, H [1 ]
Weill, F [1 ]
Maglione, M [1 ]
Cansell, F [1 ]
机构
[1] Inst Chim Mat Condensee Bordeaux, F-33608 Pessac, France
关键词
supercritical fluids; nanotechnology; coating; core-shell structures; BaTiO3@ Al2O3; ferroelectric materials; low dielectric losses;
D O I
10.1166/jnn.2005.147
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
This work highlights, for the first time, the coating of ferroelectric nanoparticles with a chemical fluid deposition process in supercritical fluids. BaTiO3 nanoparticles of about 50 nm are coated with a shell of a few nanometers of amorphous alumina and can be recovered as a dry powder for processing. The sintering of these core-shell nanoparticles gives access to a ceramic material with very interesting ferroelectric properties, in particular, dielectric losses below 1%.
引用
收藏
页码:980 / 983
页数:4
相关论文
共 23 条
[1]   Deposition of gold films and nanostructures from supercritical carbon dioxide [J].
Cabañas, A ;
Long, DP ;
Watkins, JJ .
CHEMISTRY OF MATERIALS, 2004, 16 (10) :2028-2033
[2]   Review on materials science and supercritical fluids [J].
Cansell, F ;
Aymonier, C ;
Loppinet-Serani, A .
CURRENT OPINION IN SOLID STATE & MATERIALS SCIENCE, 2003, 7 (4-5) :331-340
[3]   Electrical characterization of grain boundary decorated SrTiO3 ceramics [J].
Hofer, C ;
Weber, U ;
Waser, R .
JOURNAL OF THE EUROPEAN CERAMIC SOCIETY, 2001, 21 (10-11) :1753-1757
[4]   New application of the core-shell concept to ferroelectric nanopowders [J].
Huber, C ;
Treguer-Delapierre, M ;
Elissalde, C ;
Weill, F ;
Maglione, M .
JOURNAL OF MATERIALS CHEMISTRY, 2003, 13 (04) :650-653
[5]   Particle design using supercritical fluids: Literature and patent survey [J].
Jung, J ;
Perrut, M .
JOURNAL OF SUPERCRITICAL FLUIDS, 2001, 20 (03) :179-219
[6]   Effects of copper coating on the crystalline structure of fine barium titanate particles [J].
Liu, XH ;
Shih, WY ;
Shih, WH .
JOURNAL OF THE AMERICAN CERAMIC SOCIETY, 1997, 80 (11) :2781-2788
[7]   Low loss tunable (Ba,Sr)TiO3 ceramics utilizing intragrain concentration gradient [J].
Lubomirsky, I ;
Wang, TY ;
Deflaviis, F ;
Stafsudd, OM .
INTEGRATED FERROELECTRICS, 1999, 24 (1-4) :319-326
[8]   Control of particle growth by chemical transformation in supercritical CO2/ethanol mixtures [J].
Pessey, V ;
Garriga, R ;
Weill, F ;
Chevalier, B ;
Etourneau, J ;
Cansell, F .
JOURNAL OF MATERIALS CHEMISTRY, 2002, 12 (04) :958-965
[9]   SmCo5/Cu particles elaboration using a supercritical fluid process [J].
Pessey, V ;
Mateos, D ;
Weill, F ;
Cansell, F ;
Etourneau, J ;
Chevalier, B .
JOURNAL OF ALLOYS AND COMPOUNDS, 2001, 323 :412-416
[10]   Core-shell materials elaboration in supercritical mixture CO2/ethanol [J].
Pessey, V ;
Garriga, R ;
Weill, F ;
Chevalier, B ;
Etourneau, J ;
Cansell, F .
INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH, 2000, 39 (12) :4714-4719