Palladium-catalyzed reactions of acylzirconocene chloride with organic halides

被引：55

作者：

Hanzawa, Y ^{[1
]}

Tabuchi, N ^{[1
]}

Taguchi, T ^{[1
]}

机构：

[1] Tokyo Univ Pharm & Life Sci, Sch Pharm, Hachioji, Tokyo 1920392, Japan

来源：

TETRAHEDRON LETTERS | 1998年 / 39卷 / 34期

关键词：

complexes; coupling reactions; palladium and compounds; zirconium and compounds;

D O I：

10.1016/S0040-4039(98)01287-8

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Palladium-catalyzed reactions of nonanoylzirconocene chloride 1 with aryl halide, acid halides, and allylic halides gave the acylated compounds through a nucleophilic attack of an "unmasked" acyl anion in fair to excellent yields. In an analogous way, allylic acetate gave an acyl substituted product through the reaction of 1. (C) 1998 Elsevier Science Ltd. All rights reserved.

引用

页码：6249 / 6252

页数：4

共 10 条

[1]

[Anonymous], COMPREHENSIVE ORGANI

[2] HYDROZIRCONATION .2. OXIDATIVE HOMOLOGATION OF OLEFINS VIA CARBON-MONOXIDE INSERTION INTO CARBON-ZIRCONIUM BOND [J].

BERTELO, CA ;

SCHWARTZ, J .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1975, 97 (01) :228-230

[3]

HARADA S, IN PRESS ANGEW CHEM

[4] PALLADIUM CATALYZED REACTION OF ACYLTINS WITH ORGANIC HALIDES [J].

KOSUGI, M ;

NAKA, H ;

HARADA, S ;

SANO, H ;

MIGITA, T .

CHEMISTRY LETTERS, 1987, (07) :1371-1372

[5] SELECTIVE CARBON-CARBON BOND FORMATION VIA TRANSITION-METAL CATALYSIS .8. DOUBLE METAL CATALYSIS IN CROSS-COUPLING REACTION AND ITS APPLICATION TO STEREO-SELECTIVE AND REGIOSELECTIVE SYNTHESIS OF TRISUBSTITUTED OLEFINS [J].

NEGISHI, E ;

OKUKADO, N ;

KING, AO ;

VANHORN, DE ;

SPIEGEL, BI .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1978, 100 (07) :2254-2256

[6] HYDROZIRCONATION - NEW TRANSITION-METAL REAGENT FOR ORGANIC-SYNTHESIS [J].

SCHWARTZ, J ;

LABINGER, JA .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1976, 15 (06) :333-340

[7]

TAKACS JM, 1995, COMPREHENSIVE ORGA 2, V12, P39

[8]

Tsuji J., 1995, PALLADIUM REAGENTS C

[9] A VERSATILE ACCESS TO UNSYMMETRICAL AND SYMMETRICAL ALPHA-DIKETONES VIA ORGANOTIN REAGENTS [J].

VERLHAC, JB ;

CHANSON, E ;

JOUSSEAUME, B ;

QUINTARD, JP .

TETRAHEDRON LETTERS, 1985, 26 (49) :6075-6078

[10] TRINUCLEAR ZR2,AL MU-KETENE COMPLEXES CONTAINING BRIDGING LIGANDS - IMPLICATIONS FOR TRANSMETALATION REACTIONS AND CO REDUCTION CHEMISTRY [J].

WAYMOUTH, RM ;

SANTARSIERO, BD ;

COOTS, RJ ;

BRONIKOWSKI, MJ ;

GRUBBS, RH .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1986, 108 (07) :1427-1441

← 1 →