Why is random close packing reproducible?

被引:169
作者
Kamien, Randall D. [1 ]
Liu, Andrea J. [1 ]
机构
[1] Univ Penn, Dept Phys & Astron, Philadelphia, PA 19104 USA
关键词
D O I
10.1103/PhysRevLett.99.155501
中图分类号
O4 [物理学];
学科分类号
0702 ;
摘要
We link the thermodynamics of colloidal suspensions to the statistics of regular and random packings. Random close packing has defied a rigorous definition yet, in three dimensions, there is near universal agreement on the volume fraction at which it occurs. We conjecture that the common value of phi(rcp)approximate to 0.64 arises from a divergence in the rate at which accessible states disappear. We relate this rate to the equation of state for a hard-sphere fluid on a metastable, noncrystalline branch.
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页数:4
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