Solution-Processed Metallic Nanowire Electrodes as Indium Tin Oxide Replacement for Thin-Film Solar Cells

被引:177
作者
Krantz, Johannes [1 ]
Richter, Moses [1 ]
Spallek, Stefanie [2 ]
Spiecker, Erdmann [2 ]
Brabec, Christoph J. [1 ,3 ]
机构
[1] Univ Erlangen Nurnberg, Dept Mat Sci, I MEET WW6, D-91058 Erlangen, Germany
[2] Univ Erlangen Nurnberg, Ctr Nanoanal & Electron Microscopy CENEM, D-91058 Erlangen, Germany
[3] Bavarian Ctr Appl Energy Res ZAE Bayern, D-91058 Erlangen, Germany
关键词
silver nanowires; electrodes; organic electronics; indium tin oxide replacement; solar cells;
D O I
10.1002/adfm.201100457
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Solution processed silver nanowire (Ag NW) films are introduced as transparent electrodes for thin-film solar cells. Ag NW electrodes were processed by doctor blade-coating on glass substrates at moderate temperatures (less than 100 degrees C). The morphological, optical, and electrical characteristics of these electrodes were investigated as a function of processing parameters. For solar-cell application, Ag NW electrodes with an average transparency of 90% between 450 and 800 nm and a sheet resistivity of 10 O per square were chosen. The performance of poly(3-hexylthiophen-2,5-diyl):[6,6]-phenyl-C61-butyric acid methyl ester (P3HT:PCBM) solar cells on Ag NW electrodes was found to match the performance of otherwise identical cells on indium tin oxide. Overall, P3HT:PCBM solar cells with an efficiency of 2.5% on transparent Ag NW electrodes have been realized.
引用
收藏
页码:4784 / 4787
页数:4
相关论文
共 17 条
[1]   Transparent conductive single-walled carbon nanotube networks with precisely tunable ratios of semiconducting and metallic nanotubes [J].
Blackburn, Jeffrey L. ;
Barnes, Teresa M. ;
Beard, Matthew C. ;
Kim, Yong-Hyun ;
Tenent, Robert C. ;
McDonald, Timothy J. ;
To, Bobby ;
Coutts, Timothy J. ;
Heben, Michael J. .
ACS NANO, 2008, 2 (06) :1266-1274
[2]   Polymer-Fullerene Bulk-Heterojunction Solar Cells [J].
Brabec, Christoph J. ;
Gowrisanker, Srinivas ;
Halls, Jonathan J. M. ;
Laird, Darin ;
Jia, Shijun ;
Williams, Shawn P. .
ADVANCED MATERIALS, 2010, 22 (34) :3839-3856
[3]   Silver nanowires [J].
Graff, A ;
Wagner, D ;
Ditlbacher, H ;
Kreibig, U .
EUROPEAN PHYSICAL JOURNAL D, 2005, 34 (1-3) :263-269
[4]   Colored semitransparent conductive coatings consisting of monodisperse metallic single-walled carbon nanotubes [J].
Green, Alexander A. ;
Hersam, Mark C. .
NANO LETTERS, 2008, 8 (05) :1417-1422
[5]   Organic solar cells with solution-processed graphene transparent electrodes [J].
Wu, Junbo ;
Becerril, Hector A. ;
Bao, Zhenan ;
Liu, Zunfeng ;
Chen, Yongsheng ;
Peumans, Peter .
APPLIED PHYSICS LETTERS, 2008, 92 (26)
[6]   Solution-processed metal nanowire mesh transparent electrodes [J].
Lee, Jung-Yong ;
Connor, Stephen T. ;
Cui, Yi ;
Peumans, Peter .
NANO LETTERS, 2008, 8 (02) :689-692
[7]   Solution-Processable Graphene Oxide as an Efficient Hole Transport Layer in Polymer Solar Cells [J].
Li, Shao-Sian ;
Tu, Kun-Hua ;
Lin, Chih-Cheng ;
Chen, Chun-Wei ;
Chhowalla, Manish .
ACS NANO, 2010, 4 (06) :3169-3174
[8]  
Rodrigues V, 2002, PHYS STATUS SOLIDI B, V230, P475, DOI 10.1002/1521-3951(200204)230:2<475::AID-PSSB475>3.0.CO
[9]  
2-A
[10]   Organic solar cells with carbon nanotube network electrodes [J].
Rowell, Michael W. ;
Topinka, Mark A. ;
McGehee, Michael D. ;
Prall, Hans-Juergen ;
Dennler, Gilles ;
Sariciftci, Niyazi Serdar ;
Hu, Liangbing ;
Gruner, George .
APPLIED PHYSICS LETTERS, 2006, 88 (23)