Metal@MOF:: Loading of highly porous coordination polymers host lattices by metal organic chemical vapor deposition

被引：600

作者：

Hermes, S

Schröter, MK

Schmid, R

Khodeir, L

Muhler, M

Tissler, A

Fischer, RW

Fischer, RA ^{[1
]}

机构：

[1] Ruhr Univ Bochum, Lehrstuhl Anorgan Chem 2, D-44780 Bochum, Germany

[2] Ruhr Univ Bochum, Lehrstuhl Tech Chem, D-44780 Bochum, Germany

[3] Sud Chem AG, D-83052 Bruckmuhl, Germany

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2005年 / 44卷 / 38期

基金：

欧盟地平线“2020”;

关键词：

coordination polymers; chemical vapor deposition; heterogeneous catalysis; methanol synthesis; nanoparticles;

D O I：

10.1002/anie.200462515

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Precursors and particles captured in a net: Porous coordination polymers such as MOF-5 are efficient gas storage devices and are also able to absorb metal organic chemical vapor deposition (MOCVD) precursors (see picture, red: [(η5-C5H5)Pd(η-C3H 5)]). These incorporated compounds are easily reduced to give the corresponding metal nanoparticles. Applications in heterogeneous catalysis, for instance, methanol synthesis or hydrogenation, are described. © 2005 Wiley-VCH Verlag GmbH & Co. KGaA. (Chemical Equation Presented).

引用

页码：6237 / 6241

页数：5

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