Recent developments in the synthesis of heterocyclic derivatives by PdI2-catalyzed oxidative carbonylation reactions

被引：78

作者：

Gabriele, B ^{[1
]}

Salerno, G

Costa, M

Chiusoli, GP

机构：

[1] Univ Calabria, Dipartimento Sci Farmaceut, I-87036 Arcavacata Di Rende, Cosenza, Italy

[2] Univ Calabria, Dipartimento Chim, I-87036 Arcavacata Di Rende, Cosenza, Italy

[3] Univ Parma, Dipartimento Chim Organ & Ind, I-43100 Parma, Italy

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 2003年 / 687卷 / 02期

关键词：

alkynes; beta-amino alcohols; carbonylation; heterocycles; oxidative carbonylation; palladium;

D O I：

10.1016/S0022-328X(03)00789-7

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A simple catalytic system, consisting of PdI2 in conjunction with an excess of KI, has proven to be very valuable for the direct one-step synthesis of a variety of heterocyclic derivatives by oxidative carbonylation of suitably functionalized alkynes. The same catalyst also promoted the oxidative carbonylation of beta-amino alcohols to oxazolidin-2-ones with unprecedented catalytic efficiencies for this kind of reaction. (C) 2003 Elsevier B.V. All rights reserved.

引用

页码：219 / 228

页数：10

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