Synthesis and photophysical properties of trimetallic acetylide complexes with a 1,3,5-triazine core

被引：51

作者：

Hu, QY

Lu, WX

Tang, HD

Sung, HHY

Wen, TB

Williams, ID

Wong, GKL ^{[1
]}

Lin, ZY

Jia, GC

机构：

[1] Hong Kong Univ Sci & Technol, Dept Chem, Inst Mol Technol Drug Discovery & Synth, Kowloon, Hong Kong, Peoples R China

[2] Hong Kong Univ Sci & Technol, Open Lab Chirotechnol, Inst Mol Technol Drug Discovery & Synth, Kowloon, Hong Kong, Peoples R China

[3] Hong Kong Univ Sci & Technol, Dept Phys, Kowloon, Hong Kong, Peoples R China

来源：

ORGANOMETALLICS | 2005年 / 24卷 / 16期

关键词：

D O I：

10.1021/om0502133

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Treatment of 2,4,6-tris(4-bromophenyl)-1,3,5-triazine (2,4,6-(4-BrC6H4)(3)-1,3,5-C3N3) with HC CSiMe3 in the presence of Pd(PPh3)(4)/CuI and NEt3 produces 2,4,6-[4-(Me3SiC C)C6H4](3)-1,3,5-C3N3, which reacts with Bu4NF to yield 2,4,6-[4-(HC C)C6H4](3)-1,3,5-C3N3. Reaction of 2,4,6-[4-(HC C)C6H4](3)-1,3,5-C3N3 with AuCl(PPh3) in the presence of NEt3 produces the gold acetylide complex 2,4,6-[4-((PPh3)AuC C)C6H4](3)-1,3,5-C3N3. Treatment of 2,4,6-[4-(HC C)C6H4](3)-1,3,5-C3N3 with cis-RuCl2(dppe)(2)/NaPF6 followed by NEt3 gives 2,4,6-[4-(Cl(dppe)(2)RuC C)C6H4](3)-1,3,5-C3N3, which reacts with p-HC CC6H4R (R = OCH3, NO2) to give 2,4,6-[4-((4-RC6H4C C)(dppe)(2)RuC C)C6H4](3)-1,3,5-C3N3. The electrochemical and photo-physical properties of the new complexes have been investigated.

引用

页码：3966 / 3973

页数：8

共 110 条

[1]

Abrahams BF, 1999, ANGEW CHEM INT EDIT, V38, P1475, DOI 10.1002/(SICI)1521-3773(19990517)38:10<1475::AID-ANIE1475>3.0.CO

[2]

2-3

[3] Diimine-acetylide compounds of ruthenium: The structural and spectroscopic effects of oxidation [J].

Adams, CJ ;

Pope, SJA .

INORGANIC CHEMISTRY, 2004, 43 (11) :3492-3499

[4] Switching of molecular second-order polarisability in solution [J].

Asselberghs, I ;

Clays, K ;

Persoons, A ;

Ward, MD ;

McCleverty, J .

JOURNAL OF MATERIALS CHEMISTRY, 2004, 14 (19) :2831-2839

[5] PREPARATION AND SPECTROSCOPIC PROPERTIES OF THE ETA-2-DIHYDROGEN COMPLEXES [MH(ETA-2-H2)(PR2CH2CH2PR2)2]+ (M = FE, RU, R = PH, ET) AND TRENDS IN PROPERTIES DOWN THE IRON GROUP TRIAD [J].

BAUTISTA, MT ;

CAPPELLANI, EP ;

DROUIN, SD ;

MORRIS, RH ;

SCHWEITZER, CT ;

SELLA, A ;

ZUBKOWSKI, J .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1991, 113 (13) :4876-4887

[6]

Biradha K, 2002, ANGEW CHEM INT EDIT, V41, P3392, DOI 10.1002/1521-3773(20020916)41:18<3392::AID-ANIE3392>3.0.CO

[7]

2-V

[8] One- and two-dimensional silver-coordination networks containing π-sandwiched silver-silver interactions [J].

Bosch, E ;

Barnes, CL .

INORGANIC CHEMISTRY, 2002, 41 (09) :2543-2547

[9] INCLUSION AND AGGREGATION PROPERTIES OF ORGANOGOLD COMPLEXES - CRYSTAL-STRUCTURES OF C2(AU[P(C6H4R-3)3])2.NC6H6(R = H, N = 2-R = ME, N = 0 AND 1) [J].

BRUCE, MI ;

GRUNDY, KR ;

LIDDELL, MJ ;

SNOW, MR ;

TIEKINK, ERT .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1988, 344 (03) :C49-C52

[10] Bis(trimethylsilyl)acetylene [J].

Bruckmann, J ;

Kruger, C .

ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS, 1997, 53 :1845-1846

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