Photochemistry of 2-nitrobenzyl enol ethers: Oxidative C=C bond scission

被引：13

作者：

Yong, PK ^{[1
]}

Banerjee, A ^{[1
]}

机构：

[1] Univ N Dakota, Dept Chem, Grand Forks, ND 58202 USA

来源：

ORGANIC LETTERS | 2005年 / 7卷 / 12期

关键词：

D O I：

10.1021/ol0508072

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

2-Nitrobenzyl enol ethers, when photolyzed in the presence of air, result in an oxidative C=C bond scission, forming a ketone as the major product (> 60% yield). Enol release leads to the aldehyde as the minor product.

引用

页码：2485 / 2487

页数：3

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