Corrosion inhibition of mild steel by the new class of inhibitors [2,5-bis(n-pyridyl)-1,3,4-thiadiazoles] in acidic media

被引:237
作者
El Azhar, M
Mernari, B
Traisnel, M
Bentiss, F
Lagrenée, M
机构
[1] ENSCL, UPRES A 8012, Lab Cristallochim & Physicochim Solide, F-59652 Villeneuve Dascq, France
[2] Univ Chouaib, Fac Sci, Lab Chim Coordinat & Analyt, M-24000 El Jadida, Morocco
[3] ENSCL, UPRES EA 2698, Lab Genie Procedes Interact Fluides Reactifs Mat, F-59652 Villeneuve Dascq, France
关键词
thiadiazoles; corrosion inhibitor; mild steel; acidic media; electrochemical impedance spectroscopy; adsorption;
D O I
10.1016/S0010-938X(01)00034-8
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
The inhibitor effect of 2,5-bis(n-pyridyl)-1,3,4-thiadiazoles (n-PTH) on the corrosion of mild steel in 1 M HCl and 0.5 M H2SO4 have been investigated using weight loss and electrochemical impedance spectroscopy. Results obtained reveal that these compounds are mixed-type inhibitors and behave better in 1 M HCl than in 0.5 M H2SO4. The adsorption of n-PTH on the mild steel surface in both acidic media follows a Langmuir isotherm model. (C) 2001 Elsevier Science Ltd. All rights reserved.
引用
收藏
页码:2229 / 2238
页数:10
相关论文
共 18 条
[1]  
[Anonymous], 1993, CORROSION CHIMIE SUR
[2]   3,5-bis(n-hydroxyphenyl)-4-amino-1,2,4-triazoles and 3,5-bis(n-aminophenyl)-4-amino-1,2,4-triazoles:: a new class of corrosion inhibitors for mild steel in 1 M HCl medium [J].
Bentiss, F ;
Lagrenee, M ;
Traisnel, M ;
Mernari, B ;
Elattari, H .
JOURNAL OF APPLIED ELECTROCHEMISTRY, 1999, 29 (09) :1073-1078
[3]   The substituted 1,3,4-oxadiazoles: a new class of corrosion inhibitors of mild steel in acidic media [J].
Bentiss, F ;
Traisnel, M ;
Lagrenee, M .
CORROSION SCIENCE, 2000, 42 (01) :127-146
[4]   The corrosion inhibition of mild steel in acidic media by a new triazole derivative [J].
Bentiss, F ;
Lagrenee, M ;
Traisnel, M ;
Hornez, JC .
CORROSION SCIENCE, 1999, 41 (04) :789-803
[5]   THE ADSORPTION OF AROMATIC AMINES AT THE INTERFACE - MERCURY-AQUEOUS ACID SOLUTION [J].
BLOMGREN, E ;
BOCKRIS, JO .
JOURNAL OF PHYSICAL CHEMISTRY, 1959, 63 (09) :1475-1484
[6]  
Dus B., 1984, CORROSION NACE, V15, P175
[7]  
FOROULIS ZA, 1985, P 6 EUR S CORR INH S, V8, P130
[8]  
IOFA ZA, 1960, ZH FIZ KHIM+, V34, P1036
[9]  
JUTTNER K, 1990, ELECTROCHIM ACTA, V35, P150
[10]   CHEMICAL AND ELECTROCHEMICAL INHIBITION STUDIES OF CORROSION AND HYDROGEN SURFACE EMBRITTLEMENT .1. FE0.78B0.13SI0.09 AMORPHOUS ALLOY IN MOLAR HCL [J].
KERTIT, S ;
ARIDE, J ;
BENBACHIR, A ;
SGHIRI, A ;
ELKHOLY, A ;
ETMAN, M .
JOURNAL OF APPLIED ELECTROCHEMISTRY, 1989, 19 (01) :83-89