Bio-inorganic approach to hydrocarbon oxidation

被引：59

作者：

Moro-oka, Y ^{[1
]}

Akita, M ^{[1
]}

机构：

[1] Tokyo Inst Technol, Resources Utilizat Res Lab, Midori Ku, Yokohama, Kanagawa 2268503, Japan

来源：

CATALYSIS TODAY | 1998年 / 41卷 / 04期

关键词：

monooxygenase; reductive activation of dioxygen; epoxidation; hydroxylation;

D O I：

10.1016/S0920-5861(98)00023-6

中图分类号：

O69 [应用化学];

学科分类号：

081704 ;

摘要：

Oxidation reactions mimicking the biological oxidative processes are summarized. A dioxygen molecule can be activated by way of reductive activation within a coordination sphere of transition metal complexes, and the resulting electrophilic oxo species, which can also be generated by treatment with an oxo transfer reagent (so-called "shunt path"), exhibit oxidizing ability just like an oxene species. (C) 1998 Elsevier Science B.V. All rights reserved.

引用

页码：327 / 338

页数：12

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