Phthalazine-based dinucleating ligands afford dinuclear centers often encountered in metalloenzyme active sites

被引：46

作者：

Barrios, AM ^{[1
]}

Lippard, SJ ^{[1
]}

机构：

[1] MIT, Dept Chem, Cambridge, MA 02139 USA

来源：

INORGANIC CHEMISTRY | 2001年 / 40卷 / 05期

关键词：

D O I：

10.1021/ic000889k

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The dinucleating ligand 1,4-bis(2,2'-dipyridylmethyl)phthalazine (bdptz) forms stable dinuclear complexes with most of the biologically active first-row transition metal ions including manganese, iron, nickel, copper, and zinc.

引用

页码：1060 / +

页数：6

共 32 条

[1]

[Anonymous], 1998, SMART VERS 5 05

[2] Amide hydrolysis effected by a hydroxo-bridged dinickel(II) complex: Insights into the mechanism of urease [J].

Barrios, AM ;

Lippard, SJ .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1999, 121 (50) :11751-11757

[3] Interaction of urea with a hydroxide-bridged dinuclear nickel center: An alternative model for the mechanism of urease [J].

Barrios, AM ;

Lippard, SJ .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2000, 122 (38) :9172-9177

[4]

BARRIOS AM, IN PRESS INORG CHEM

[5] BIOMIMETIC CHEMISTRY AND ARTIFICIAL ENZYMES - CATALYSIS BY DESIGN [J].

BRESLOW, R .

ACCOUNTS OF CHEMICAL RESEARCH, 1995, 28 (03) :146-153

[6]

CAN RV, 1969, CAN J CHEM, V47, P4141

[7] THROUGH-SPACE POLAR-PI EFFECTS ON THE ACIDITY AND HYDROGEN-BONDING CAPACITY OF CARBOXYLIC-ACIDS [J].

CHEN, CT ;

SIEGEL, JS .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1994, 116 (13) :5959-5960

[8] Manganese enzymes with binuclear active sites [J].

Dismukes, GC .

CHEMICAL REVIEWS, 1996, 96 (07) :2909-2926

[9] A ONE-POT SYNTHESIS OF M-TERPHENYLS VIA A 2-ARYNE SEQUENCE [J].

DU, CJF ;

HART, H ;

NG, KKD .

JOURNAL OF ORGANIC CHEMISTRY, 1986, 51 (16) :3162-3165

[10] CRYSTAL-STRUCTURE AND ELECTRONIC-PROPERTIES OF AMMINE[TRIS(2-AMINOETHYL)AMINE]COPPER(II) DIPERCHLORATE AND POTASSIUM PENTA-AMMINECOPPER(II) TRIS(HEXAFLUOROPHOSPHATE) [J].

DUGGAN, M ;

RAY, N ;

HATHAWAY, B ;

TOMLINSON, G ;

BRINT, P ;

PELIN, K .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1980, (08) :1342-1348

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