Intramolecular SNAr reactions as a route to complexes of hybrid cyclopentadienyl-phosphine ligands:: synthesis of a rhodium complex of the first η5,η1,η1-cyclopentadienyl-phosphine-thioether ligand

被引:16
作者
Bellabarba, RM [1 ]
Nieuwenhuyzen, M [1 ]
Saunders, GC [1 ]
机构
[1] Queens Univ Belfast, Sch Chem, Belfast BT9 5AG, Antrim, North Ireland
来源
JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS | 2001年 / 05期
关键词
D O I
10.1039/b010244j
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
A convenient synthetic route to hybrid cyclopentadienyl-phosphine complexes is demonstrated by the high yield synthesis of the complex [RhCl{eta (5),eta (1),eta (1)-C5Me4CH2C6F4P-(C6F5)C6H4SMe}][BF4].
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页码:512 / 514
页数:3
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