Molecular and supramolecular architectures of silver(I) and copper(I) complexes of 2,6-pyridinediylbis(2-pyridinyl)methanone

被引：20

作者：

Chen, XD ^{[1
]}

Mak, TCW ^{[1
]}

机构：

[1] Chinese Univ Hong Kong, Dept Chem, Hong Kong, Hong Kong, Peoples R China

来源：

JOURNAL OF MOLECULAR STRUCTURE | 2005年 / 748卷 / 1-3期

关键词：

copper(I); silver(I); metallacyclphane; 2-pyridyl ketone; 2,6-pyridinediylbis(2-pyridinyl)methanone;

D O I：

10.1016/j.molstruc.2005.03.030

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Four silver(l) and copper(l) complexes derived from the ligand 2,6-pyridinediylbis(2-pyridinyl)methanone (L) have been synthesized and their structures determined by X-ray diffraction. Different anion coordinating abilities lead to two kinds of infinite chains in [{Ag(L)}(ClO4)](infinity) (1) and [{Ag(L)(NO3)}(CH3CN)-C-.](infinity) (2), in which ligand L exhibits different coordinating modes. In the isomorphous complexes [Cu(HL')](2)(BF4)(2)(.)2H(2)O (3) and [Cu(HL')](2)(ClO4)(2)(.)2H(2)O (4), L undergoes methanolysis at only one carbonyl group to form the monoketal HL', while the other one remains intact. (c) 2005 Elsevier B.V. All rights reserved.

引用

页码：183 / 188

页数：6

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