Electroluminescence from triplet metal-ligand charge-transfer excited state of transition metal complexes

被引:756
作者
Ma, YG [1 ]
Zhang, HY
Shen, JC
Che, CM
机构
[1] Jilin Univ, Key Lab Supramol Struct & Spect, Changchun 130023, Peoples R China
[2] Univ Hong Kong, Dept Chem, Hong Kong, Hong Kong
关键词
electroluminescence; triplet excited state; metal-ligand charge transfer; transition metal complexes;
D O I
10.1016/S0379-6779(97)04166-0
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
Triplet metal-ligand charge-transfer (MLCT) excited-state emissions of some osmium(II) complexes Os(CN)(2)(PPh3)(2)X (X = bipyridine derivatives or anthroline derivatives) are enhanced upon incorporation into the poly(N-vinyl carbazole) (PVK) matrix. By employing a cell of indium-tin oxide (ITO)-coated glass/Os complex:PVK/2-(4-biphenyl)-5-(4-tert-butyl-phenyl)-1,3,4-oxadiazole (PBD)/Al configuration , a stable and uniform red electroluminescence is observed over 8 V d.c. bias. (C) 1998 Elsevier Science S.A. All rights reserved.
引用
收藏
页码:245 / 248
页数:4
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