Synthesis of liquid crystalline polyaniline derivatives and their orientational behaviors under magnetic field

被引：17

作者：

Goto, H

Akagi, K ^{[1
]}

Itoh, K

机构：

[1] Univ Tsukuba, Inst Mat Sci, Tsukuba, Ibaraki 3058573, Japan

[2] Natl Res Inst Met, Tsukuba Magnet Lab, Tsukuba, Ibaraki 3050003, Japan

来源：

SYNTHETIC METALS | 2001年 / 117卷 / 1-3期

关键词：

polyaniline derivatives; liquid crystalline phase transition; macroscopic alignment;

D O I：

10.1016/S0379-6779(00)00544-0

中图分类号：

T [工业技术];

学科分类号：

08 ;

摘要：

We have synthesized novel liquid crystalline (LC) polyaniline derivative by introducing LC group into the ortho-position of the phenylene ring in the main chain. The polymers in the mesophase, irrespective of oxidized and neutral forms, exhibited the deeply purple colored fan-shaped textures under polarizing optical microscope, by which the LC phase was assigned to a smectic one. Subsequently, the polymer was macroscopically aligned under LC phase by using magnetic filed of 10T. The formation of mono-domain LC structure was confirmed through the observation of perfectly aligned optical texture. (C) 2001 Elsevier Science B.V. All rights reserved.

引用

页码：91 / 93

页数：3

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