Supertetrahedra in sulfides:: Matter against mathematical series?

被引:57
作者
Férey, G
机构
[1] Inst Univ France, F-78035 Versailles, France
[2] Inst Lavoisier, UMR 8637, CNRS, UVSQ, F-78035 Versailles, France
关键词
electroluminescence; microporous materials; nanomaterials; sulfides; supertetrahedra;
D O I
10.1002/anie.200201621
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The game continues... Self-assembled sulfide supertetrahedra can be used to generate porous solids with unusual electoluminescence and semiconducting properties. Recent advances, including the discovery of corner-linked superclusters (see picture) and super-supertetrahedral clusters, may lead to materials, the properties of which could be superior to the best quantum dots known to date.
引用
收藏
页码:2576 / 2579
页数:4
相关论文
共 43 条
[1]  
[Anonymous], 1998, ANGEW CHEM, V110, P48
[2]   HYDROTHERMAL CHEMISTRY OF THE SILICATES .8. LOW-TEMPERATURE CRYSTAL GROWTH OF ALUMINOSILICATES, AND OF SOME GALLIUM AND GERMAINIUM ANALOGUES [J].
BARRER, RM ;
BAYNHAM, JW ;
BULTITUDE, FW ;
MEIER, WM .
JOURNAL OF THE CHEMICAL SOCIETY, 1959, (JAN) :195-&
[3]  
BEDARD RL, 1989, STUD SURF SCI CATAL, V49, P375
[4]   Structure of microporous QUI-MnGS-1 and in situ studies of its formation using time-resolved synchrotron x-ray powder diffraction [J].
Cahill, CL ;
Ko, YH ;
Hanson, JC ;
Tan, KM ;
Parise, JB .
CHEMISTRY OF MATERIALS, 1998, 10 (05) :1453-1458
[5]   A novel 3-dimensional open framework sulfide based upon the [In10S20]10- supertetrahedron:: DMA-InS-SB1 [J].
Cahill, CL ;
Ko, YH ;
Parise, JB .
CHEMISTRY OF MATERIALS, 1998, 10 (01) :19-21
[6]   Synthesis and structure of MnGe4S10 center dot(C6H14N2)center dot 3H2O: A novel sulfide framework analogous to zeolite Li-A(BW) [J].
Cahill, CL ;
Parise, JB .
CHEMISTRY OF MATERIALS, 1997, 9 (03) :807-811
[7]   Hydrothermal synthesis, structure and magnetic properties of [Fe-3(PO4)(3)F-2,H3N-(CH2)(4)-NH3]: The analog of the three-dimensional gallophosphate structure-type ULM-3 [J].
Cavellec, M ;
Riou, D ;
Greneche, JM ;
Ferey, G .
JOURNAL OF MAGNETISM AND MAGNETIC MATERIALS, 1996, 163 (1-2) :173-183
[8]   [Fe-4(PO4)(4)F-2(H2O)(3)]center dot[C6H14N2] or ULM-12, the first magnetic ferric phosphate with an open structure: Hydrothermal synthesis, structure, and magnetic properties [J].
Cavellec, M ;
Riou, D ;
Ninclaus, C ;
Greneche, JM ;
Ferey, G .
ZEOLITES, 1996, 17 (03) :250-260
[9]  
Cheetham A. K., 1999, ANGEW CHEM, V111, P3466
[10]  
Cheetham AK, 1999, ANGEW CHEM INT EDIT, V38, P3268, DOI 10.1002/(SICI)1521-3773(19991115)38:22<3268::AID-ANIE3268>3.0.CO